Tài liệu Khoa học vật liệu hydrocarbon và hóa học vật liệu nano carbon

Contents
Preface
xv
Organizers and sponsors xvii
International Advisory and Organizing Committee of ICHMS’2005 xix
Program Committee xxi
Words of Welcome xxiii
The Peculiarities of Hydrogenation of Platinum Fullerides
Z.A. Matysina, S.Yu. Zaginaichenko, D.V. Schur, V.B. Molodkin,
T.N. Veziroglu 1
Investigation of Mechanism of Fullerene Dissolution in Aromatical
Hydrocarbons
N.S. Anikina, D.V. Schur, S.Yu. Zaginaichenko, O.Ya. Krivushchenko,
O.V. Mil’to, A. Kale 19
Conductivity of C60 Fullerene Crystals under Multi-step Dynamic
Compression up to 300 KBar
V.V. Avdonin, V.I. Postnov, K.L. Kagan, D.V. Shakhray, V Fortov,
A.F. Shestakov, R.K. Nikolaev, N.S. Sidorov, V.V. Kveder,
Yu.A. Osip’yan 37
Gas Interstitial Fullerenes Precipitated from the Solution of C60 in
1,2-dichlorobenzene
Y.M. Shulga, S.A. Baskakov, V.M. Martynenko, Y.G. Morozov,
V.N. Vasilets, V.F. Razumov, D.V. Schur, A. Michtchenko 41
Mg2NiHx as Procatalyst of Synthesis of Carbon Nanofibers
A.A. Volodin, P.V. Fursikov, B.P. Tarasov 53
Electronic Structure Exploration of Active Element Surface for
Hydrogen Sensor Based on WO3-x Nanoparticles
A.M. Korduban, A.P. Shpak, M.M. Medvedskij 59
Isotopic effect in hydrogen and nitrogen solid solutions in -Ti
I. Khidirov, L.N. Padurets, S.Yu. Zaginaichenko, S.Kh. Sultanova 65
Synthesis, Properties, and Assimilation Methods of Aluminium Hydride
U. Mirsaidov 77
v
vi CONTENTS
Influence of Hydrogen Ordering on the Proton Spin-Lattice Relaxation
Time in Lanthanum Superstoichiometric Dihydrides LaH2+c
N.Z. Namoradze, I.G. Ratishvili 87
Creation of Hydrogen - Selective Tubular Composite Membranes
Based on Pd-Alloys: I. Improvement of Ceramic Support with
Ni Layer Deposition
O.K. Alexeeva, D.M. Amirkhanov, A.A. Kotenko, M.M. Chelyak 95
Hydrides Formation in Hollow Cylinder
N.M. Vlasov, I.I. Fedik 105
Interband Electron Transitions in the Alloyed C60 Films with the Ionic
Defect Formation
.P. Dmytrenko, N.P. ulish, Yu.I. Prylutskyy, N Belyi,
L.V. Poperenko, V.S. Stashchuk, .L. Pavlenko, Pogorelov,
N.S.nikina, D.V. Schur
Computer Simulation of the Electron Beam Irradiation Effect
on the Modification of Carbon Nanotubes
M.V. Makarets, Yu.i. Prylutskyy, D.V. Schur, H. Bernas, P. Scharff
111
119
Theoretical Study and Experimental Investigation of Hydrogen
Absorption by Carbon Nanomaterials
G.N. Churilov, A.S. Fedorov, P.B. Sorokin, S.A. Marchenko,
P.V. Novikov, N.V. Bulina, Yu.S. Martinez, A. Gedanken 127
Radiation Induced Phenomena on Electronic and Protonic Conductions
of Compact Hydride-Electrolyte Fuel Cell
B. Tsuchiya, S. Nagata, K. Saito, K. Toh, T. Shikama 133
Defectoscopy and Perspectives Related to Metallic Materials Adoptable
in Hydrogen Storage Pressure Tanks Production
M. Rogante, F.G. Cesari, V.T. Lebedev 139
Electrophysical Properties of the Nanocarbon Materials
L.Yu. Matzui, I.V. vsienko, Len, L.L. Vovchenko, Yu.I. Prylutskyy,
S.Yu. Zaginaichenko, P. Eklund, F. Normand 149
Free Radical Halogenation of Carbon Nanomaterials at Low
Temperatures
.I. Mikhaylov, V Pakhomova, S.I. uzina, S Baskakov, Yu
Shul’ga., A.A. Volodin, V.E. Muradyan 155
Hydrogen Concentration Dependence on Thermal and Electrical
Conductivities of Metal-Hydride Composite Materials
B. Tsuchiya, K. Konashi, S. Nagata, T. Shikama, M. Yamawaki 159
CONTENTS
Irradiation Effect of Gamma-Ray on the Proton-Conducting Polymer
Y. Konishi, B. Tsuchiya, S. Nagata, K. Toh, T. Shikama 165
A.D. Rud, A.E. Perekos, A.P. Shpak, V.N. Uvarov, N.I. Kuskova,
Zh.N. Ishchenko, V.M. Ogenko
169
Promising Catalysts for H2 - O2 Fuel Cells (Review)
K.V. Lykhnytskyi, M. Jaskua, V.Z. Barsukov 177
Description of Phase Equilibriums in Intermetallic Compounds
within the Perturbation Theory
V.S. Marinin, Yu.F. Shmal’ko, K.R. Umerenkova 187
MgH2–Carbon Composites for Hydrogen Storage
R.V. Lukashev, S.N. Klyamkin, B.P. Tarasov 193
Synthesis of Carbon Nanostructures in Gaseous and Liquid Medium
D.V. Schur, A.G. Dubovoy, S.Yu. Zaginaichenko, V.M. Adejev,
A.V. Kotko, V.A. Bogolepov, A.F. Savenko, A.D. Zolotarenko,
S.A Firstov, V.V. Skorokhod 199
Pt Nanoclusters on Carbon Nanomaterials for Hydrogen Fuel Cells
N.S. Kuyunko, S.D. Kushch, V.E. Muradyan, A.A. Volodin,
V.I. Torbov, B.P. Tarasov 213
The Configurational Heat Capacity of Fullerite over the Region
of scl fccl Phase Transition
Z.A. Matysina, S.Yu. Zaginaichenko, D.V. Schur, T.A. Trifonova 219
Comments Concerning Parameters of the Short-Range Order
Evolution Determined from the Data on Kinetics of a
Heat-Capacity Relaxation for Lu–H Alloy
T.M. Radchenko, V.A. Tatarenko 229
Trifluoromethylation of Endohedral Metallofullerenes M@C82 (M = Y,
Ce): Synthesis, Isolation and Structure
I.E. Kareev, V.P. Bubnov, E.E. Laukhina, D.N. Fedutin, E.B. Yagubskii,
S.F. Lebedkin, I.V. Kuvychko, S.H. Strauss, O.B. Boltalina 235
Synthesis, Isolation and Spectroscopic Study of a Series of Endohedral
Metallofullerenes Y2@C84, Ce2@C78 and M@C82 (M = Y, La, Ce, Gd)
I.E. Kareev, V.P. Bubnov, S.F. Lebedkin, E.B. Yagubskii 243
Formation of Ordered Carbon Nanostructures at Pyrolysis of Hydrated
Cellulose Containing the Metals of Ferrous Subgroup
A.M. Safonova, L.E. Shpilevskaya, S.V. Batura, O.V. Bezhok 251
vii
Electrical Explosion Technology for Novel Carbon Nanomaterials
Production
viii CONTENTS
New Design of Electron Gun for Field Emission Light Sources with
Carbon Fibers Cathode
M.Yu. Leshukov, E.P. Sheshin 255
Physical Processes on the Surface of Field Emission Cathodes Based
on Carbon Nanostructural Materials
V.S. Bormashov, E.P. Sheshin 259
New Technique of Field Emission Cathodes Preparation by Low
Temperature Deposition from Ethanol Vapor
A.M. Lamanov, A.N. Redkin, E.P. Sheshin 265
Fullerene Synthesis in Helium Flow at Atmospheric Pressure
N.V. Bulina, V.A. Lopatin, P.V. Novikov, N.G. Vnukova,
W. Krätschmer, G.N. Churilov 269
Atomic Hydrogen Adsorption on Boron Nitride Nanotube Surfaces
V.A. Margulis, E.E. Muryumin, O.B. Tomilin 275
Investigations of the Influence of Different Additives to the Lanthanum
Rich Mischmetal
L. Grinberga, J. Kleperis, G. Vaivars, A. Nechaev, F.W. Poulsen,
A.S. Pedersen 279
On Electrochemical Deposition of Fullerenes and their Compounds
from Solutions
N.G. Khotynenko, D.V. Schur, S.Yu. Zaginaichenko, A.F. Savenko,
V.M. Adeev, A.A. Rogozinskaya, O.V. Mil’to, B.P. Tarasov,
Yu.M. Shul’ga
287
Novel Carbon Nanostructures Produced by Electrochemical Method
L.S. Lysyuk, V.M. Ogenko, S.V. Volkov, A.P. Shpak 297
Structure of Solid Amorphous Phases of Water and Capture of
Molecules 4, 2 in Multistructures of Ice
S.A. Beznosyuk, A.A. Perezhogin 303
Some Lessons of the Chemistry of Metal Hydrides in the Light
of Problems of Hydrogen Accumulation
O.K. Alekseeva, L.N. Padurets, P.P. Parshin, A.L. Shilov 313
About Interaction of Hydrogen with Spherical Particles
of 5-1 Type Alloy
V.N. Fokin, E.E. Fokina, V.I. Torbov, B.P. Tarasov, S.P. Shilkin,
R.A. Andrievsky 321
CONTENTS
Application of Layered InSe and GaSe Crystals and Powders for Solid
State Hydrogen Storage
Yu.I. Zhirko, Z.D. Kovalyuk, M.M. Pyrlja, V.B. Boledzyuk 325
Interaction of Mg-REM-Ni Alloys and Composites with Hydrogen
D.N. Borisov, P.V. Fursikov, V.A. Yartys, A.S. Pedersen, B.P. Tarasov 341
Calorimetric Investigation of Hydrogen Interaction with ZrMn2
E.Yu. Anikina, E.V. Gerasimova, V.N. Verbetsky 347
Structure of NbVCoD2.5 Synthesized under High Gaseous Pressure
S.A. Lushnikov, V.N. Verbetsky, V.P. Glazkov, V.A. Somenkov 357
Structural and Methodical Features of the Installation for Investigations
of Hydrogen-Sorption Characteristics of Carbon Nanomaterials
and Their Composites
A.F. Savenko, V.A. Bogolepov, K.A. Meleshevich, S.Yu. Zaginaichenko,
D.V. Schur, M.V. Lototsky, V.K. Pishuk, L.O. Teslenko, V.V. Skorokhod 365
Improvement of Hydride Heat Devices Overall Performance
Yu.I. Shanin 383
Computer Modeling of Ions +, 3+, 52
+ Transport in Nanostructural
Supermolecules of Water
S.A. Beznosyuk, A.A. Perezhogin 399
Industrial Technologies for Production of LaNi5-Based Hydride
Materials
V.P. Mordovin, A.V. Kasimtsev, V.P. Alekhin, V.V. Zhigunov 407
Quantitative Application of Lateral Force Microscopy for Carbon
Nanotubes Investigation
A.S. Baturin, A.A. Chouprik, E.P. Sheshin 415
The Correlation between Ionicity of Metal-Hydrogen Bonds
in Hydrides and their Thermal Firmness
V.D. Dobrovolsky 421
About Manner and Mechanisms of Reduction of Thermal Firmness
of Mg -, Ti -, Y – Based Mechanical Alloys
O.G. Ershova, V.D. Dobrovolsky, Yu.M. Solonin, R.A. Morozova 429
Electronic Structure and Stability of Higher Fullerenes
V.I. Kovalenko, A.R. Khamatgalimov 437
Investigation of the Hydrogen Interaction with Ti0.9Zr0.1Mn1.3V0.5
by Calorimetric Method
E.Yu. Anikina, V.N. Verbetsky 443
ix
x CONTENTS
Investigation of the Physical Properties of Materials for Fuel Elements
and Work up of Limit State Criteria for Hydrogen Containing Solid
Materials with Acoustic Microscope Defectoscopy Methods
A.I. Kustov, I.A. Migel 451
Electrolytic Production of Carbon Nano-Tubes in Chloride-Oxide Melts
under Carbon Dioxide Pressure
I.A. Novoselova, N.F. Oliynyk, S.V. Volkov 459
Investigation of Delayed Hydride Cracking in the Zr-2,5% Nb Alloy
A. Grybenas, R. Levinskas, V. Makarevicius 467
Soliton Lattices in Carbon Nanotubes
M.B. Belonenko, E.V. Demushkina, N.G. Lebedev 471
Investigation of Low-Temperature Radiation Living Radical
Polymerization of Vinyl Monomers with Fullerene 60 by Optical
Spectroscopy
V Pakhomova, D.A. Gordon, .I Mikhailov 481
Influence of Hydrogen on Magnetocrystalline Anisotropy
of TbFe6Co5Ti Single Crystal
N.Yu. Pankratov, S.A. Nikitin, K.P. Skokov, W. Iwasieczko,
I.V. Telegina, H. Drulis, V.V. Zubenko, Yu.G. Pastushenkov,
O. Gutfleisch, A. Handstein, K.-H. Müller 485
Study of Isotopic Effect for Hydrogen and Deuterium Adsorption on
Nanoporous Carbon (NPC) at 67-78 K
S.D. Bondarenko, I.A. Alekseev 493
Modeling of Dehydration and Dehydrogenation in Zirconia with Anion
Impurity
D.L. Savina, V.V. Tokiy, N.V. Tokiy, T.E. Konstantinova 499
Study of Fe-MgO Catalyst Structural Transformations in the Process of
Pyrolytic Synthesis of Carbon Nanomaterials
A.A. Novakova, J.V. Il’ina, E.I. Stepanov, N.N. Uferov, E.G. Rakov 509
Carbon Nanomaterials on the Base of Catalytic Hydrocarbon Pyrolysis:
Development and Perspective Use
A.G. Tkachev, S.V. Blinov, N.R. Memetov 515
Solutions of Polystyrene as a Carbonization Precursor for the Matryx
Synthesis of Carbon Nanostructures
S.V. Volkov, V.M. Ogenko, L.V. Dubrovina, O.V. Holdun, A.I. Senkevich,
N.I. Danylenko 521
CONTENTS
Nanocarbon Materials
A.V. Melezhyk, Yu.I. Sementsov, V.V. Yanchenko 529
The Production of Hydrides in Titanic Powders under Different Ways
of Manufacturing
Shapovalova, E.P. Babenko 539
Electrochemical Properties of Nanodispersed Diamond
G.P. Bogatyreva, M.A. Marinich, G.A. Bazaliy 547
Technical and Technological Methods of Realization of Steam Catalytic
Conversion of Natural Gas with a Methane-Water Proportion Close to
Stoichiometric Ratio
V.S. Igumnov 555
Magnetic & Thermodynamic Studies of CoO (I) & CoO (II)
V.K. Goswami, B. Ghosh, K.S. De 563
Structure and Formation of Films of Zirconia-Based Solid Electrolyte
V.B. Malkov, V.N. Strekalovskiy, A.V. Malkov, V.G. Puchin, B.V. Shulgin,
O.V. Malkov 567
EPR Spin Probe Study of Carbon Nanoparticles Hydration Properties in
Aqueous Dispersions
S.P. Rozhkov, A.S. Goryunov, N.N. Rozhkova 571
Nanostructured Carbon Materials Based on IR-Pyrolized
Polyacrylonitrile
G.P. Karpacheva, L.M. Zemtsov, K.A. Bagdasarova, D.G. Muratov,
M.N. Efimov, M.M. Ermilova, N.V. Orekhova 577
Molecular Hydrogen Evolution: Photocatalytic Activity of Mesoporous
TiO2-Containing Metal Composites
.V. Korzhak, A. E. Raevskaya, A.L. Stroyuk, N.I. Yermokhina,
V.I. Litvin, V Bukhtiyarov, P.A. Manorik, V.G. Ilyin, S.Ya.Kuchmii 587
Change of Curie Temperature and Effective Exchange Fields in
Ferrimagnetic R2Fe14B Compounds upon Hydrogenation
I.S. Tereshina, E.A. Tereshina, S.A. Nikitin, O.D. Chistyakov,
G.S. Burkhanov, L. Folcik, H. Drulis 599
Magnetic Properties of Some ER2FE14BHx Hydrides
R. Bezdushnyi, I.S. Tereshina, R. Damianova, S.A. Nikitin,
E.A. Tereshina, G.S. Burkhanov, O.D. Chistyakov 605
The Modern Data of Obtaining of Firm Hydrogen
V.N. Adamovich, L.F. Dubykivsky, G.M. Ochrimenko 613
xi
xii CONTENTS
TDS-Spectra of Hydride Powder Decomposition: Modelling with
Size Reduction Effect
Yu.V. Zaika, N.I. Rodchenkova 619
Activated Carbon and Hydrogen Adsorption Storage
L.L. Vasiliev, L.E. Kanonchik, .G. Kulakov, D.A. Mishkinis 633
Influence of Hydrogen on Magnetic and Magnetoelastic Properties of
Lu2Fe17 Single Crystal
E.A. Tereshina, A.V. Andreev, I.S. Tereshina, S.A. Nikitin, W. Iwasieczko,
H. Drulis 653
The Problem of Hydrogen Permeation into the Boron Doped
Electrodeposited Nickel Films
A.V. Zvyagintseva, Y.G. Kravtsova 661
Hydrogen Permeation and Nickel Films Structure Correlation
A.V. Zvyagintseva, Y.G. Kravtsova 665
Inhibition of Hydrogen Permeability by TiN: Evaluation of Kinetic
Parameters
V.V. Popov, E.A. Denisov 671
Determination of Hydrogen Binding Energy in Various Materials by
Means of Absolute Measurements of its Concentration in Solid Probe
A.M. Polyanskiy, V.A. Polyanskiy, D.B. Popov-Diumin 681
Peculiarities of Low Temperature Interaction of Mechanically Activated
Titanium Hydride with Nitrogen and Oxygen
M.P. Savyak, T.A. Lyudvinska, V.B. Muratov, V.Ye. Matsera,
L.P. Isayeva, I.V. Uvarova 693
Metal Hydride Use for Solar Energy Accumulation
L.G. Shcherbakova, D.B. Dan’ko, G.Ya. Kolbasov, I.A. Rusetskii,
V.B. Muratov, I.A. Kossko, Yu.M. Solonin 699
Electronic Structure of Carbon Nanotubes of Variable Diameter
A.P. Popov, I.V. Bazhin 707
Cubic Polymerized Structures of Small Fullerenes C20, C24, C28, C32
A.P. Popov, I.V. Bazhin 713
Electronic Structure of t-junctions of Carbon Nanotubes
A.P. Popov, I.V. Bazhin, E.S. Bogoslovskaya 721
Metal-Carbon Nanostructured Membrane Catalysts
M.M. Ermilova, N.V. Orekhova, G.F. Tereshchenko, G.P. Karpacheva,
R.A. Penzin, L.M. Zemtsov 729
CONTENTS
Carbon under Pressure and Radiation
V.P. Glazkov, V.A. Nikolaenko, V.A. Somenkov 735
On Some Special Features of Carbon Nanostructure Fabrication in Argon
arc Discharge
V.I. Podgorny, A.N. Yakovlev, B.Z. Belashev 745
Positron Spectroscopy of Liquid Crystalline Organic Materials
Containing C60 Fullerenes
I.E. Fomenko, M.M. Nishchenko, S.P. Likhtorovich, T.A. Mirnaya,
D.V. Bylina 753
Properties of PTFE – MWNT Composite Materials
Yu.I. Sementsov, A.V. Melezhyk, M.L. Pyatkovsky, V.V. Yanchenko,
N.A. Gavrilyuk, G.P. Prikhod’ko, A.I. Senkevich, S.L. Revo,
E.A. Ivanenko 757
Multifunctional Integrated Fuel Cells Electrode on Macroporous
Silicon. Design & Technology
V.V. Starkov 765
Structural Effects in Ultrafine Diamond under Thermal
and Thermal-Baric Actions
A.I. Bykov, Ya.V. Zaulichnyy, L.P. Isaeva, L.A. Klochkov,
A.V. Kovalev, T.F. Lobunets, R.A. Morozova, G.S. Oleynik,
A.A. Rogozinskaya, I.I. Timofeeva, T.V. Tomila 773
Development of the Approach to the Synthesis of Individual Isomers of
Bis(organo)[60]fullerenes. Bis(azahomo)fullerenes
I.P. Romanova, G.G. Yusupova, A.A. Larionova, S.K. Latyupov,
A.A. Balandina, O.G. Sinyashin 779
Binding of a Fluorine Atom to the Sidewall of Single-Walled Carbon
Nanotubes
V.A. Margulis, E.E. Muryumin, O.B. Tomilin 789
Influence of Impurities and Defects on Electronic Structure of Carbon
Nanotubes
A.P. Popov, I.V. Bazhin 795
Electronic Structure of Y-junctions of Carbon Nanotubes
A.P. Popov, I.V. Bazhin, E.S. Bogoslovskaya 801
The Structure and Properties of Iron Alloys with ultradispersed by
Educations of Free Carbon
D Baranov, A Baranov 805
Effect of Hydrogen on Delayed Fracture of Maraging Steels
B.M. Efros, V.V. Berezovskaya, N.V. Shishkova, I.P. Konakova,
N.B. Efros, L.V. Loladze, V.N. Varyukhin 811
xiii