Tài liệu Khái quát về hóa học nano

Contents
Preface ix
About the authors xi
1 Introduction 1
1.1 What is supramolecular chemistry? 1
1.2 Selectivity 4
1.3 Supramolecular interactions 17
1.4 Supramolecular design 26
References 27
Suggested further reading 27
2 Solution host–guest chemistry 29
2.1 Introduction: guests in solution 29
2.2 Macrocyclic versus acyclic hosts 30
2.3 Cation binding 36
2.4 Anion binding 52
2.5 Metal-containing receptors 66
2.6 Simultaneous cation and anion receptors 73
2.7 Neutral-molecule binding 82
2.8 Supramolecular catalysis and enzyme mimics 97
References 104
3 Self-assembly 107
3.1 Introduction 107
3.2 Biological self-assembly 114
3.3 Ladders, polygons and helices 121
3.4 Rotaxanes, catenanes and knots 133
3.5 Self-assembling capsules 156
References 167
4 Solid state supramolecular chemistry 171
4.1 Introduction 171
4.2 Zeolites 172
4.3 Clathrates 179
4.4 Clathrate hydrates 187
viii contents
4.5 Crystal engineering 194
4.6 Coordination polymers 209
References 225
5 Nanochemistry 229
5.1 Introduction 229
5.2 Nanomanipulation 233
5.3 Molecular devices 237
5.4 Self-assembled monolayers (SAMs) 254
5.5 Soft lithography 264
5.6 Nanoparticles 266
5.7 Fullerenes and nanotubes 272
5.8 Dendrimers 277
5.9 Fibres, gels and polymers 279
5.10 Nanobiology and biomimetic chemistry 284
References 293
Index 297