Tài liệu hạt nano kim loại để làm chất xúc tác và khoa học vật liệu

Contents
Part I: General Aspects
1. General Features of Metal Nanoparticles Physics and Chemistry
Gu¨ nter Schmid . 3
2. Metal Nanoclusters: Synthesis and Strategies for their Size Control
Helmut Bo¨ nnemann and Kyatanahalli S. Nagabhushana . 21
3. Recent Progress in Bimetallic Nanoparticles: Their Preparation, Structures and Functions
Naoki Toshima, Hu Yan, and Yukihide Shiraishi 49
4. Metal Nanoclusters: Electronic Aspects and Physico-Chemical Characterization
La´ szlo´ Guczi, Zolta´n Pa´ szti, and Ga´ bor Pet+o . 77
5. Applications of Metal Nanoclusters in Nanoelectronics
Eva Koplin and Ulrich Simon 107
6. Nanoscale Characterization of Metal Nanoclusters by Means of X-Ray Diffraction (XRD) and
Transmission Electron Microscopy (TEM) Techniques
Patrizia Canton, Pier Francesco Fazzini, Carlo Meneghini, Alvise Benedetti, and Giulio Pozzi 129
7. Platinum Nanoclusters’ Size and Surface Structure Sensitivity of Catalytic Reactions
Robert M. Rioux, Hyunjoon Song, Peidong Yang, and Gabor A. Somorjai . 149
8. Metal Nanoclusters in Catalysis: Effects of Nanoparticle Size, Shape, and Structure
F. Klasovsky and P. Claus 167
9. Relevance of Metal Nanoclusters Size Control in Gold(0) Catalytic Chemistry
Masatake Haruta . 183
10. Metal Nanoclusters Supported on Cross-Linked Functional Polymers: A Class of Emerging
Metal Catalysts
Marco Zecca, Paolo Centomo, and Benedetto Corain . 201
11. Digestive Ripening, or ‘‘Nanomachining,’’ to Achieve Nanocrystal Size Control
Kenneth J. Klabunde, Christopher M. Sorensen, Savka I. Stoeva, Bagavatula L. V. Prasad,
Alexander B. Smetana, and Xiao-Min Lin . 233
Part II: Methodologies
12. Gold Nanoparticles: From Preparation to Catalytic Evaluation
Michele Rossi, Cristina Della Pina, Ermelinda Falletta, and Roberto Matarrese 253
13. Photocatalytic Deposition and Plasmon-Induced Dissolution of Metal Nanoparticles on TiO2
Tetsu Tatsuma and Kazuki Matsubara 263
ix
14. Synthesis of Metal Nanoclusters upon Using Ion Implantation
P. Mazzoldi and G. Mattei 269
15. Size Controlled Pd Nanoparticles Anchored to Carbon Fiber Fabrics: Novel Structured Catalyst
Effective for Selective Hydrogenation
Lioubov Kiwi-Minsker, Natalia Semagina, and Albert Renken . 293
16. Synthesis of Morphologically Controlled Pt Nanoparticles and Their Application in Catalytic Reactions
Akane Miyazaki and Ioan Balint 301
17. Multipods and Dendritic Nanoparticles of Platinum: Colloidal Synthesis and Electrocatalytic Property
Hong Yang, Xiaowei Teng, and Sean Maksimuk 307
18. Spreader-Bar Structures as Molecular Templates for Electrochemical Synthesis of Nanoparticles
Vladimir M. Mirsky . 321
19. Solvent and Simple Ion-Stabilized Metal Nanoclusters: Chemical Synthesis and Application
Yuan Wang and Xiaodong Wang . 327
20. Microgels as Exotemplates in the Synthesis of Size Controlled Metal Nanoclusters
Andrea Biffis 341
21. Magnetron Sputtering to Prepare Supported Metal Catalysts
Gabriel M. Veith, Andrew R. Lupini, and Nancy J. Dudney 347
22. Gold Colloidal Nanoparticles Sized to be Suitable Precursors for Heterogeneous Catalysts
F. Porta and L. Prati 355
23. Liquid Phase Structural Control of Mono- and Bimetallic Nanoparticles
Toshiharu Teranishi, Masafumi Nakaya, and Masayuki Kanehara 361
24. Solvent-Free Controlled Thermolysis for Facile Size-Regulated Synthesis of Metal and Alloy
Nanoparticles
Masami Nakamoto, Mari Yamamoto, and Yukiyasu Kashiwagi . 367
25. Systematic Synthesis of Monolayer-Protected Gold Clusters with Well-Defined Chemical Compositions
Tatsuya Tsukuda, Hironori Tsunoyama, and Yuich Negishi . 373
26. Template Synthesis and Catalysis of Metal Nanoclusters in Ordered Mesoporous Silicas
Paresh L. Dhepe and Atsushi Fukuoka . 383
27. Liquid-Phase Reductive Deposition of Metal Nanoclusters Selective onto Oxide Surfaces
Atsushi Muramatsu, Hideyuki Takahashi, and Katsutoshi Yamamoto . 391
28. Production of Metal Nanoparticles by Plants and Plant-Derived Materials
Jorge L. Gardea-Torresdey, Jose R. Peralta-Videa, Jason G. Parsons, Ntebogeng S. Mokgalaka,
and Guadalupe de la Rosa 401
29. Gel-Type Cross-Linked Functional Polymers as Template in the Synthesis of Size Controlled Metal
Nanoclusters
B. Corain, P. Centomo, C. Burato, and P. Canton . 413
30. Size and Shape Selective Synthesis of Metal Nanoparticles by Seed-Mediated Method and the Catalytic
Activity of Growing Microelectrodes (GME) and Fully Grown Microelectrodes (FGME)
Tarasankar Pal and Snigdhamayee Praharaj 419
31. Metal Nanoparticles Dispersed in Solution: Tests to Identify the Catalyst Nature
Montserrat Go´ mez and Isabelle Favier 427
x Contents
32. Metal Vapor-Derived Nanostructured Catalysts in Fine Chemistry: The Role Played by Particle Size
in the Catalytic Activity and Selectivity
Giovanni Vitulli, Claudio Evangelisti, Anna Maria Caporusso, Paolo Pertici, Nicoletta Panziera,
Sergio Bertozzi, and Piero Salvadori . 437
33. Wet Preparation of Metal Nanoparticles and Their Immobilization on Silicon Substrates
Tetsu Yonezawa, Yoshinori Yamanoi, and Hiroshi Nishihara . 453