Sách Extraction Of Aromatics From Naphtha With Ionic Liquids : From Solvent Developme

Thảo luận trong 'Sách Khoa Học' bắt đầu bởi Thúy Viết Bài, 5/12/13.

  1. Thúy Viết Bài

    Thành viên vàng

    Bài viết:
    198,891
    Được thích:
    167
    Điểm thành tích:
    0
    Xu:
    0Xu
    AROMATICS REMOVAL FROM NAPHTHA

    The objective of this study was the development of a separation technology for the
    selective recovery and purification of aromatic compounds benzene, toluene, ethylbenzene
    and xylenes (BTEX) from liquid ethylene cracker feeds. Most ethylene cracker feeds
    contain 10 – 25% of aromatic components, depending on the source of the feed (naphtha or
    gas condensate). The aromatic compounds are not converted to olefins and even small
    amounts are formed during the cracking process in the cracker furnaces. Therefore, they
    occupy a part of the capacity of the furnaces and they put an extra load on the separation
    section of the C5+- aliphatic compounds. If a major part of the aromatic compounds present
    in the feed to the crackers could be separated up stream of the furnaces, it would offer
    several advantages: higher capacity, higher thermal efficiency and less fouling.

    The current processes for the separation of aromatic and aliphatic hydrocarbons are
    either suitable for aromatic concentrations of 20% or more, such as extraction, extractive
    distillation and azeotropic distillation, or show low aromatic/aliphatic selectivities and/or
    have low capacities. Therefore, it was investigated, whether and how the performance of
    adsorption/desorption, membrane separation and extraction could be drastically improved
    at low aromatics content by using new separating agents. After a short literature study,
    adsorption/desorption was discarded for further work because potentially suitable zeolite
    adsorbents, for instance X and Y types, would result in tremendous technical problems
    during desorption and its scale up to large capacities appeared unfavourable.