Tài liệu Chlorine and Chloramine Removal with Activated Carbon

Thảo luận trong 'Hóa Học' bắt đầu bởi Thúy Viết Bài, 5/12/13.

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    Municipalities routinely began
    using chlorine to treat drinking
    water starting in 1908 with
    Jersey City, NJ. Its use has helped to virtually eliminate diseases
    like typhoid fever, cholera and dysentery in the US and other
    developed countries. Globally the World Health Organization
    (WHO) estimates that 3.4 million people in underdeveloped
    countries die every year from water-related diseases.
    Use of chlorine in water can produce an undesirable taste;
    therefore, many consumers prefer to remove it. Disinfection
    byproducts (DBPs) may also unintentionally form when chlorine
    and other disinfectants react with natural organic matter that is
    in the water. To reduce DBP formation, many municipalities are
    switching to monochloramine.
    Monochloramine treatment was first used in Ottawa,
    Ontario, Canada in 1916 and in Denver, CO in 1917. Use of
    monochloramine took a downturn during World War II due to
    ammonia shortages. Currently the US EPA estimates more than
    30 percent of larger US municipalities use monochloramine.
    It’s a common misperception that activated carbon removes
    chlorine and monochloramine from water by adsorption.
    Understanding how activated carbon
    removes chlorine and monochloramine
    from water is critical to the design and
    operation of such systems.
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    .The addition of any of these to water will producehypochlorous acid (HOCl). This disassociates into hypochlorite
    ions (OCl-) to some degree. (The reaction is summarized
    below).
    Cl2 + H2O → HOCl + H+ + Cl–
    HOCl - → H+ + OCl+
    The ratio of hypochlorous acid and hypochlorite ion in water
    is dependent upon pH level and, to a much lesser degree, water
    temperature. The ratio of hypochlorous acid and hypochlorite ion
    at various water pH and temperature is shown in Table 1.
     

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